Gennaro Gattuso will replace Carlo Ancelotti as Napoli head coach, according to Sky in Italy.
The 41-year-old is set to sign a six-month contract with the Serie A club, who will have the option to extend the deal by a further year.
Ancelotti was sacked on Tuesday night, just hours after leading Napoli into the last 16 of the Champions League with a 4-0 win over Genk.
Gennaro Gattuso played under Carlo Ancelotti at AC Milan
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Gattuso and Ancelotti won two Champions Leagues and Serie A together at Milan
However, that was their first win in 10 matches and Ancelotti's relationship with club president Aurelio De Laurentiis had become strained this season.
Gattuso, who played under Ancelotti at AC Milan, is set to take Napoli training on Wednesday.
The 41-year-old is set to sign a six-month contract with the Serie A club, who will have the option to extend the deal by a further year.
Ancelotti was sacked on Tuesday night, just hours after leading Napoli into the last 16 of the Champions League with a 4-0 win over Genk.
Gennaro Gattuso played under Carlo Ancelotti at AC Milan
Image:
Gattuso and Ancelotti won two Champions Leagues and Serie A together at Milan
However, that was their first win in 10 matches and Ancelotti's relationship with club president Aurelio De Laurentiis had become strained this season.
Gattuso, who played under Ancelotti at AC Milan, is set to take Napoli training on Wednesday.